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Yahoo!奇摩知識+ - 分類問答 - 科學常識 - 已解決
Yahoo!奇摩知識+ - 分類問答 - 科學常識 - 已解決
請問化學氧化還原滴定
Jul 8th 2013, 18:00

草酸氫鈉與酸性 KMnO4 的反應:
MnO4
+ 8H + 5e Mn²⁺ + 4H2O
HC2O4 H + 2CO2 + 2e

MnO4 的當量數 = 0.1 x (40/1000) = 0.004
HC2O4
的當量數 = 0.004
HC2O4
的當量濃度 = 0.004 / (20/1000) = 0.2N
HC2O4
的體積莫耳濃度 = 0.2 / 2 = 0.1 M

草酸氫鈉與 KOH 的反應:
HC2O4
H + C2O4²⁻
OH
+ H H2O

HC2O4 的當量濃度 = 0.1 N
HC2O4
的當量數 = 0.1 x (20/1000) = 0.002
KOH (OH
) 的當量數 = 0.002
KOH
的體積 = 0.002 / 0.1 = 0.02 L = 20 mL

參考資料 賣女孩的火柴

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